4. Explain why diisopropylamine is a stronger base than aniline nh2 diisopropylamine aniline?
Friday, April 07, 2023
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Question: 4. Explain why diisopropylamine is a stronger base than aniline nh2 diisopropylamine aniline?
Diisopropylamine is a stronger base than aniline due to the greater availability of its lone pair of electrons, which can be more easily donated to a proton. In diisopropylamine, the nitrogen atom is attached to two bulky isopropyl groups, which increase the electron density on the nitrogen atom, making it more basic. In contrast, in aniline, the lone pair of electrons on the nitrogen atom is partially delocalized into the aromatic ring, decreasing its availability to accept a proton and making it a weaker base.
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